Abstract

Stellated bimetallic nanostructures are a new class of plasmonic colloids in which the interplay between composition and overall architecture can provide tunable optical properties and new functionality. However, decoupling the complex compositional and structural contributions to the localized surface plasmon resonance (LSPR) remains a challenge, especially when the monometallic counterparts are not synthetically accessible for comparison. Here, stellated Au–Pd nanocrystals (NCs) with Oh symmetry are used as a model system to decouple structural and complex compositional effects on LSPR. Single-particle correlation of the LSPR with the structure of octopodal Au–Pd NCs was achieved using optical dark-field spectroscopy with scanning electron microscopy. These measurements were compared to calculations of the optical properties of structurally similar Au-only octopods by the finite difference time domain method. This comparison enabled the role of complex composition, which was determined by scanning transmission electron microscopy–energy-dispersive spectrometry measurements, on the LSPR to be elucidated from the structural contributions. This methodology provides a powerful framework to guide the design of new plasmonic colloids through both structure and composition.

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Dragnea Research is at the forefront of multidisciplinary innovation, exploring the intersection of nanoscale optics, quantum photonics, physical virology, and bio-architected hybrid materials with 3D nanoscale order. Their latest publications highlight groundbreaking advancements in fields such as self-assembly, optics and spectroscopy, and the physical manipulation of virus-like particles (VLPs) for chemical imaging and surface modifications. Drawing from their expertise in using near-field scanning techniques and laser-induced effects, these works showcase how nanoscale phenomena can be harnessed for applications in material science, virology, and beyond. The accompanying visual mosaic underscores the diverse range of their research, from probing molecular dynamics to the development of 3D-ordered structures, all united by a commitment to pushing the boundaries of applied and theoretical science.